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PHOTOCATALYTIC HYDROGEN HARVESTING: RECENT ADVANCES, CHALLENGES, AND FUTURE PERSPECTIVES

Sushil Kumar Pandey

Department of Chemistry, St. Xavier’s College, Ranchi - 834001, India.

48-56

Vol: 9, Issue: 2, 2019

Receiving Date: 2019-04-12 Acceptance Date:

2019-05-28

Publication Date:

2019-06-14

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Abstract

Over the past few decades, global energy demand has increased dramatically, placing immense pressure on already depleting fossil fuel reserves. This escalating demand, combined with rising concerns over climate change and environmental pollution, has intensified the need for a sustainable and clean energy supply. Conventional fossil fuels not only accelerate environmental degradation but also create economic instability and geopolitical tensions, underscoring the urgency of transitioning to renewable energy technologies. In this scenario, the development of efficient and sustainable energy production methods has become indispensable. Among the various alternatives, hydrogen stands out as a highly promising clean energy carrier. As the most abundant element in the universe, hydrogen possesses high energy density and produces only water upon combustion, making it an environmentally benign fuel. It can be generated through multiple pathways, with photocatalysis emerging as one of the most attractive approaches. Photocatalysis offers a distinctive strategy for hydrogen production by utilizing sunlight to drive chemical reactions, enabling the harvesting of hydrogen gas from water or biomass resources. By directly converting solar energy into chemical energy, this process presents a sustainable route toward clean fuel generation.

Keywords: photocatalysis; hydrogen harvesting; band gap; water splitting; photoreforming

References

  1. Abe, R., Sayama, K., & Sugihara, H. (2005). Development of new photocatalytic water splitting into H₂ and O₂ using two different semiconductor photocatalysts and a shuttle redox mediator IO₃⁻/I⁻. Journal of Physical Chemistry B, 109(33).
  2. Ahluwalia, R. K., & Peng, J. K. (2009). Automotive hydrogen storage system using cryo-adsorption on activated carbon. International Journal of Hydrogen Energy, 34(13), 5476–5487.
  3. Bahnemann, D., Henglein, A., Lilie, J., & Spanhel, L. (1984). Flash photolysis observation of the absorption spectra of trapped positive holes and electrons in colloidal TiO₂. Journal of Physical Chemistry, 88(4).
  4. Bahruji, H., Bowker, M., Davies, P. R., Mazroai, L. S., Dickinson, A., Greaves, J., James, D., Millard, L., & Pedrono, F. (2010). Sustainable H₂ gas production by photocatalysis. Journal of Photochemistry and Photobiology A: Chemistry, 216(2–3), 115–118.
  5. Balat, M. (2008). Potential importance of hydrogen as a future solution to environmental and transportation problems. International Journal of Hydrogen Energy, 33(15), 4013–4029.
  6. Ball, M., & Weeda, M. (2015). The hydrogen economy – Vision or reality? International Journal of Hydrogen Energy, 40(25), 7903–7919.
  7. Chen, X., & Mao, S. S. (2007). Titanium dioxide nanomaterials: Synthesis, properties, modifications and applications. Chemical Reviews, 107(7).
  8. Chiarello, G. L., Aguirre, M. H., & Selli, E. (2010). Hydrogen production by photocatalytic steam reforming of methanol on noble metal-modified TiO₂. Journal of Catalysis, 273(2), 182–190.
  9. Christoforidis, K. C., & Fornasiero, P. (2017). Photocatalytic hydrogen production: A rift into the future energy supply. ChemCatChem, 9(9).
  10. Colmenares, J. C., Magdziarz, A., Aramendia, M. A., Marinas, A., Marinas, J. M., Urbano, F. J., & Navio, J. A. (2011). Influence of the strong metal support interaction effect (SMSI) of Pt/TiO₂ and Pd/TiO₂ systems in the photocatalytic biohydrogen production from glucose solution. Catalysis Communications, 16(1).
  11. Fu, X., Long, J., Wang, X., Leung, D. Y. C., Ding, Z., Wu, L., Zhang, Z., Li, Z., & Fu, X. (2008). Photocatalytic reforming of biomass: A systematic study of hydrogen evolution from glucose solution. International Journal of Hydrogen Energy, 33(22), 6484–6491.
  12. Fujishima, A., & Honda, K. (1972). Electrochemical photolysis of water at a semiconductor electrode. Nature, 238(5358).
  13. Hong, Y., Liu, E., Shi, J., Lin, X., Sheng, L., Zhang, M., Wang, L., & Chen, J. (2018). A direct one-step synthesis of ultrathin g-C₃N₄ nanosheets from thiourea for boosting solar photocatalytic H₂ evolution. International Journal of Hydrogen Energy, 44(14), 7194–7204.
  14. Ipsakis, D., Voutetakis, S., Seferlis, P., Stergiopoulos, F., & Elmasides, C. (2009). Power management strategies for a stand-alone power system using renewable energy sources and hydrogen storage. International Journal of Hydrogen Energy, 34(16).
  15. Kawai, T., & Sakata, T. (1980). Conversion of carbohydrate into hydrogen fuel by a photocatalytic process. Nature, 286(5772).
  16. Khan, S. U. M., Al-Shahry, M., & Ingler, W. B. (2002). Efficient photochemical water splitting by a chemically modified n-TiO₂. Science, 297(5590).
  17. Lai, Q., Paskevicius, M., Sheppard, D. A., Buckley, C. E., Thornton, A. W., Hill, M. R., Gu, Q., Mao, J., Huang, Z., Liu, H. K., Guo, Z., Banerjee, A., Chakraborty, S., Ahuja, R., & Zinsou, K. F. A. (2015). Hydrogen storage materials for mobile and stationary applications: Current state of the art. ChemSusChem, 8(17).
  18. Li, H. W., Yan, Y., Orimo, S. I., Züttel, A., & Jensen, C. M. (2011). Recent progress in metal borohydrides for hydrogen storage. Energies, 4(1).
  19. Luo, N., Jiang, Z., Shi, H., Cao, F., Xiao, T., & Edwards, P. P. (2009). Photo-catalytic conversion of oxygenated hydrocarbons to hydrogen over heteroatom-doped TiO₂ catalysts. International Journal of Hydrogen Energy, 34(1), 125–129.
  20. Maeda, K., Teramura, K., Lu, D., Takata, T., Saito, N., Inoue, Y., & Domen, K. (2006). Photocatalyst releasing hydrogen from water. Nature, 440(7082).
  21. Mazloomi, K., & Gomes, C. (2012). Hydrogen as an energy carrier: Prospects and challenges. Renewable and Sustainable Energy Reviews, 16(5).
  22. Montini, T., Gombac, V., Sordelli, L., Delgado, J. J., Chen, X., Adami, G., & Fornasiero, P. (2011). Nanostructured Cu/TiO₂ photocatalysts for H₂ production from ethanol and glycerol aqueous solutions. ChemCatChem, 3(3), 574– 577.
  23. Osgood, R. (2006). Photoreaction dynamics of molecular adsorbates on semiconductor and oxide surfaces. Chemical Reviews, 106(10).
  24. Rude, L. H., Nielsen, T. K., Ravnsbæk, D. B., Bösenberg, U., Ley, M. B., Richter, B., Arnberg, L. M., Dornheim, M., Filinchuk, Y., Besenbacher, F., & Jensen, T. R. (2011). Tailoring properties of borohydrides for hydrogen storage: A review. Physica Status Solidi A: Applications and Materials Science, 208(8).
  25. Sakata, T., & Kawai, T. (1981). Heterogeneous photocatalytic production of hydrogen and methane from ethanol and water. Chemical Physics Letters, 80(2), 341–344.
  26. Slamet, Tristantini, D., Valentina, Ibadurrohman, M. (2012). Photocatalytic hydrogen generation from glycerol and water using Pt-loaded N-doped TiO₂ nanotube photocatalyst. International Journal of Energy Research, 11.
  27. Sun, L., & Bolton, J. R. (1996). Determination of the quantum yield for the photochemical generation of hydroxyl radicals in TiO₂ suspensions. Journal of Physical Chemistry, 100(10).
  28. Taniguchi, Y., Yoneyama, H., & Tamura, H. (1983). Hydrogen evolution on surface-modified silicon powder photocatalysts in aqueous ethanol solutions. Chemical Letters, 12(3), 269–272.
  29. Thompson, T. L., & Yates, J. T. (2006). Surface science studies of the photoactivation of TiO₂ new photochemical processes. Chemical Reviews, 106(10), 4428–4453.
  30. Verhelst, S. (2014). Recent progress in the use of hydrogen as a fuel for internal combustion engines. International Journal of Hydrogen Energy, 39(2). https://doi.org/10.1016/j.ijhydene.2013.10.102
  31. Wang, C. Y., Rabani, J., Bahnemann, D. W., & Dohrmann, J. K. (2002). Photonic efficiency and quantum yield of formaldehyde formation from methanol in the presence of various TiO₂ photocatalysts. Journal of Photochemistry and Photobiology A: Chemistry, 148(1–3).
  32. Zhou, M., Li, Y., Peng, S., Lu, G., & Li, S. (2012). Effect of epimerization of D-glucose on photocatalytic hydrogen generation over Pt/TiO₂. Catalysis Communications, 18, 21–25.
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